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Photochemistry of Triphenylmethylcyclopentadiene

Name: Photochemistry of Triphenylmethylcyclopentadiene
Creator: Weigl, Stefan
Keywords: Chemistry, photochemistry, direct irradiation, thermolytic isomerization

descriptionPublicationkeyboard_double_arrow_right Thesis 01 Sep 1975 Canada English

Authors: Weigl, Stefan;

handle: 11375/20673 , 11375/9206

Photochemistry of Triphenylmethylcyclopentadiene

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Abstract

The products and mechanism of the photolytic rearrangement of the equilibrium mixture of triphenylmethylcyclopentadienes have been studied. Direct irradiation of the equilibrium mixture of triphenylmethylcyclopentadienes yields 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene. Photolysis with a triplet sensitizer yields dimeric products in addition to 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene. Thermolytic isomerization of 5,6,6-triphenylbicyclo{3.1.0}hex-2-ene is reported. The predominant isomer in the equilibrium mixture of triphenylmethylcyclopentadiene has been established as 2-triphenylmethylcyclopentadiene.

Master of Science (MSc)

Thesis

Country

Canada

Related Organizations

McMaster University
Canada

Keywords

Chemistry, photochemistry, direct irradiation, thermolytic isomerization

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