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CONICET Digital
Article . 2017
License: CC BY NC SA
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Spectrophotometric determination of the deltamethrin

Authors: Gimenez, L. I.; Michellod, A. M. M.; Jorge, M. J.; Pila, Andrea Natalia; Bordón, Alexander Germán; Profeta, Mariela Inés; Romero, Jorge Marcelo; +1 Authors

Spectrophotometric determination of the deltamethrin

Abstract

In the province of Corrientes is found highest production of indoor plants from all Argentina, specially in the northeast of this province. This is because the low frequency orthelack of frosts, allowing a lower cost in the production, since heating is not needed. In this type of cultive is commonly used thedeltamethrin, as the result of this, the validation of a simple method comparable with the gas chromatography for the determination of this Pesticide on both, irrigation and consumption water, was studied. In this work, a spectrophotometric method is proposed for the determination of deltamethrin inirrigation water from the area of flower crops located in the Department of Concepción in the province of Corrientes. Deltamethrin solutions in a range from 0,025 to 1 mg/L on irrigation water were prepared. The absorbance spectrum was scanned between 200 and 400 nm. The maximum absorbance was found at 220 nm. A calibration curve in the range from 0.025 to 1 mg/L, responded to A = (0.3246± 0.0224) C + (0.0096 ± 0.0068) with R2 = 0.998. The % RSD was 0.961 indicating good repeatability for the analytical procedure. The accuracy in the recovery experience was 99.0 - 109.6%. The statistical comparison using the t-test and the F-test indicates that there are no significant differences between GC and spectrophotometric methods, with a confidence level of 95%. The specificity and intermediate accuracy tests were satisfactory.

Fil: Pila, Andrea Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Modelado e Innovación Tecnológica. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Modelado e Innovación Tecnológica; Argentina

Fil: Bordón, Alexander Germán. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Departamento de Química; Argentina

Fil: Profeta, Mariela Inés. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Departamento de Química; Argentina

Fil: Romero, Jorge Marcelo. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Departamento de Química; Argentina

Fil: Michellod, A. M. M.. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Departamento de Química; Argentina

Fil: Jorge, Nelly Lidia. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Departamento de Química; Argentina

Fil: Gimenez, L. I.. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Departamento de Química; Argentina

Fil: Jorge, M. J.. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Departamento de Química; Argentina

Country
Argentina
Keywords

https://purl.org/becyt/ford/1.4, https://purl.org/becyt/ford/1, DFT, PYRETHROID, UV

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
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