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CONICET Digital
Article . 2003
License: CC BY NC SA
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Efecto del encalado en suelos contaminados por lodos piríticos

Authors: Martín Peinado, Francisco; Simon, Mariano; Garcia, Inés; Bouza, Pablo Jose; Dorronsoro, Carlos; Aguilar Ruiz, José;

Efecto del encalado en suelos contaminados por lodos piríticos

Abstract

Para analizar el efecto que tiene el carbonato cálcico en la contaminación de los suelos por oxidación de lodos piríticos, adicionamos diferentes cantidades de CaCO3 (entre 1% y 25%) a un suelo no carbonatado. A 10 g de cada una de las muestras le añadimos 100 cm3 de una solución contaminante procedente de la oxidación de lodos piríticos con H2O2. El encalado elevó el pH del suelo, favoreciendo la precipitación de los elementos disueltos. Cuando el pH6,0, además de los hidroxisulfatos de hierro, precipitaron también hidróxidos de hierro (la razón molar Fe/S llega a 14 a pH 6,5) y el Zn precipitado se elevó hasta el 95%. Por tanto, un pH del suelo en torno a 6,5 sería suficiente para asegurarse la precipitación de los distintos contaminantes y evitar la extensión de la contaminación a las capas freáticas o a otros ecosistemas próximos.

To analyse the effect of calcium carbonate on the soil pollution caused by the oxidation ofpyrite tailings, we added 10 different quantities of CaC03(between 1% and 25%) to a non-carbonatedsoil. In each case, for each 10 g of soil, we added 100 cm3of a contaminated solution from the tailingsoxidized with H2O2. The liming raised the soil pH, favouring the precipitation of the dissolved elementsin the contaminating solution. At soil pH6, in addition to Fe hydroxysulphates, Fe hydro-xides also precipitated (the Fe/S molar ratio reaching 14 at pH 6.5), and Zn adsorption rose to 95%.Consequently, a rise in soil pH to 6.5 would ensure the precipitation of Cu, As and Zn, thereby preven-ting the spread of these contaminants to the groundwater and surrounding ecosystems.

Fil: Bouza, Pablo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Centro Nacional Patagónico; Argentina

Fil: Martín Peinado, Francisco. Universidad de Granada; España

Fil: Dorronsoro, Carlos. Universidad de Granada; España

Fil: Aguilar Ruiz, José. Universidad de Granada; España

Fil: Simon, Mariano. Universidad de Almería.; España

Fil: Garcia, Inés. Universidad de Almería.; España

Country
Argentina
Keywords

ADSORCIÓN, ADSORPTION, ENCALADO, https://purl.org/becyt/ford/1.5, HEAVY METALS, METALES PESADOS, LODOS PIRÍTICOS, LIMING, PYRITE TAILINGS, https://purl.org/becyt/ford/1

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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