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Superhydrophobic Anti-Ice Nanocoatings

Authors: Knausgård, Kjetil;

Superhydrophobic Anti-Ice Nanocoatings

Abstract

Atmospheric icing from supercooled droplets in the atmosphere can have catastrophic consequences for a number of man-made structures in regions with cold climate and at high altitude, resulting in accidents with both socioeconomic losses and loss of human lives. To mitigate the icing problem, active de-icing involving chemical, thermal and mechanical techniques have been developed to remove ice that has already accumulated. These techniques are sub-optimal, however, as they are plagued with problems such as high energy consumption, hazard to the environment, high economic costs, and need for frequent reapplication. This thesis takes a look at an entirely different approach, namely utilizing superhydrophobic surfaces to reduce or eliminate the accumulation and adhesion of ice from the outset. Much of the research in the field of superhydrophobicity has involved surfaces with open-cell structures, e.g. pillar-like surfaces and surfaces with bumps and valleys. It has been reported that surfaces with closed cells have a comparative advantage in that they are better at retaining their hydrophobic properties under pressure. This thesis investigates the wetting properties (which are often closely tied to icephobic properties) of closed-cell structures further, using LAMMPS simulations. The simulations show that wetting on these surfaces satisfies the well-known theories of Wenzel and Cassie-Baxter. However, on the small scale on which the simulations were carried out, the effect of tuning the roughness scale is not as predicted by theory. Furthermore, no comparative advantage against open-cell structures could be demonstrated for the closed-cell surfaces. A physical experiment was also carried out, in which the influence of water condensation on the dynamic behavior of water droplets on a nearly-superhydrophobic black silicon surface was tested. The results confirm a well-known problem: Condensation severely deteriorates the water repellency of hydrophobic surfaces. The literature review and experiments in this thesis shows that superhydrophobic surfaces have a great potential for use in anti-icing applications, demonstrating delayed freezing, reduced ice accumulation, and reduced ice adhesion. Nevertheless, major problems are yet to be solved, including deterioration of icephobicity due to mechanical damage, and reduced icephobicity in humid conditions.

Keywords

MTNANO Nanoteknologi, energi og miljø, ntnudaim:8341, Nanoteknologi for materialer

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green