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Síntesis estereoselectivas de lactonas y compuestos espiroacetálicos de origen natural

Authors: Álvarez Bercedo, Paula;

Síntesis estereoselectivas de lactonas y compuestos espiroacetálicos de origen natural

Abstract

La Tesis titulada Síntesis estereoselectivas de compuestos lactónicos y espiroacetálicos de origen natural y desarrollada por Paula Álvarez Bercedo ha consistido en la síntesis total de los siguientes productos naturales: 1. Síntesis estereoselectiva de la estructura asignada al producto natural feigrisólido A, lo que ha permitido corregir la estructura no sólo del feigrisólido A y del feigrisólido B, demostrando que sus éstas coinciden con las de los ácidos nonáctico y homononáctico, respectivamente. 2. Síntesis enantioselectiva los espiroacetáles aculeatinas A, B, y D. 3. Síntesis enantioselectiva de la lactona insaturada dodoneína, lo que ha permitido demostrar que la estructura asignada a la misma era correcta, como también su configuración absoluta. 4. Síntesis estereoselectiva de la estructura asignada al pandangólido 1. Los datos espectroscópicos del producto sintético y natural, sin embargo, no coincidían lo que hace necesario llevar a cabo una revisión de las configuraciones absoluta y relativa de este metabolito.

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Spain
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Keywords

Química orgánica en la industria químico-farmacéutica, 547, Síntesis y estructura de productos naturales, Synthesis and structure of natural products

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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