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[{Pt]

descriptionPublicationkeyboard_double_arrow_right Article English Journal:Angewandte Chemie (International ed. in English), volume 39 (issn: 1521-3773, Copyright policy )
Authors: , Xu; , Souma; , Heaton; , Jacob; , Kanamori;

pmid: 10649377

[{Pt]

Abstract

Prolonged evacuation of [{Pt(CO)(3)}(2)](2+) (1), the first homoleptic, dinuclear, cationic platinum(I) carbonyl complex, results in reversible disproportionation. Complex 1 was formed by dissolution of PtO(2) in concentrated H(2)SO(4) under an atmosphere of CO [Eq. (a)], and completely characterized by NMR ((13)C, (195)Pt), IR, and Raman spectroscopy.

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