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Full-Text: http://hdl.handle.net/10495/28059
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Oxidación alílica de monoterpenos con metaloftalocianinas

descriptionPublicationkeyboard_double_arrow_right Article 02 May 2022 Colombia Spanish; Castilian Publisher:Universidad Tecnológica De Pereira
Authors: González Rodríguez, Lina María; Villa Holguín, Aida Luz; Montes de Correa, Consuelo; Sorokin, Alexander;

handle: 10495/28059

Oxidación alílica de monoterpenos con metaloftalocianinas

Abstract

RESUMEN: Se presentan los resultados de la oxidación alílica de los monoterpenos limoneno y a-pineno usando metaloftalocianinas inmovilizadas en sílica como catalizadores biomiméticos. Se evaluó el efecto del metal en la producción de carvona y verbenona, observándose el siguiente orden de reactividad: Fe > Co> Cr > Mn > Cu. Los mayores rendimientos hacia verbenona, 15%, se obtuvieron con los catalizadores FePcS-S y CoPcS-S

ABSTRACT: Results of allylic oxidation of limonene and a-pinene monoterpenes using silica inmovilized metallophthalocyanines as biomimetic catalyts are presented. The effect of the metal was evaluated on the production of verbenone and carvone. The following order of reactivity was observed: Fe > Co> Cr > Mn > Cu. Higher yields to verbenone, 15%, were obtained over FePcS-S and CoPcS-S.

COL0001941

Country
Colombia
Related Organizations
Keywords

Limoneno, Oxidación alílica, Limonene, Metaloftalocianinas

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
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