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Evaluación de pretratamientos químicos sobre materiales lignocelulósicos

Authors: Morales Vélez, Sonia Patricia; Quintero Díaz, Juan Carlos;

Evaluación de pretratamientos químicos sobre materiales lignocelulósicos

Abstract

RESUMEN: La eficiencia de la producción de etanol a partir de materiales lignocelulósicos depende en alto grado de la remoción de lignina, la que limita la hidrólisis de la celulosa y la posterior fermentación. En este trabajo se determinó el efecto de diferentes pretratamientos químicos sobre la composición química y cristalinidad en los materiales lignocelulósicos, aserrín de madera, bagazo de caña y cascarilla de arroz. Los pretratamientos evaluados se llevaron a cabo aplicando ácido sulfúrico o hidróxido de sodio o la combinación de ambos sobre el material. Con la aplicación del pretratamiento combinado genera las mayores remociones de lignina. Para bagazo de caña se obtuvo una remoción de lignina del 80,6%, mientras que para aserrín y cascarilla de arroz la remoción fue del 46,7%. Sin embargo, se observó una pérdida apreciable de celulosa, del 30,7% para el bagazo y 15,58% para la cascarilla. El análisis por difractometría de rayos X, reveló un incremento de la cristalinidad para el aserrín y el bagazo de caña.

ABSTRACT: The efficiency in ethanol production from lignocellulosic materials depends on high grade on the degree of lignin removal. Lignin presence limits cellulose hydrolysis and fermentation. In this work, was determined the effect of different chemical pretreatments on chemical composition and crystallinity on the lignocellulosic materials, wood chips, cane bagasse, and rice husks. Pretreatments evaluated were carried out applying sulfuric acid or sodium hydroxide or their combination over each material. The combined pretreatment allowed to obtain the highest lignine removal. For cane bagasse it was obtained an 80.6% of lignine removal, while for wood chip and rice husks lignine was removed in 46.7%. However one important cellulose loss of 30.7% was observed from bagasse cane and 15.8% from rice husks. DRX analysis showed an increase in the crystallinity for wood chip and cane bagasse.

Country
Colombia
Keywords

Aserrín, Lignine removal, Rice husk, Cane bagasse, Bagazo de caña, Cascarilla de arroz, Remoción de lignina, 600, Difractometría de rayos X, 630

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
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