η6-Arene complexes of Ni(ii), efficient catalysts for 1,3-butadiene and styrene polymerization

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2003 English Publisher:Royal Society of Chemistry (RSC)Journal:Chem. Commun. (issn: 1359-7345, eissn: 1364-548X,

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Authors: Cámpora, Juan; Conejo, María del Mar; Reyes, Manuel L.; Mereiter, Kurt; Passaglia, Elisa;

doi: 10.1039/b209838e

pmid: 12610974

handle: 10261/97094

η6-Arene complexes of Ni(ii), efficient catalysts for 1,3-butadiene and styrene polymerization

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Abstract

A simple procedure for the preparation of cationic arene complexes of Ni(II) of composition [Ni(eta 6-ArX)(eta 3-C3H5)]+[BAr'4]- (X = OH, H) is reported. These compounds are shown to behave as highly active catalysts for the polymerization of 1,3-butadiene and styrene.

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