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DIGITAL.CSIC
Article . 2013 . Peer-reviewed
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Thaumasite formation in hydraulic mortars by atmospheric SO^ deposition

Authors: Blanco-Varela, María Teresa; Martínez-Ramírez, S.; Sabbioni, C.; Zappia, G.; Toumbakari, E. E.; Aguilera, J.; Palomo, Ángel; +2 Authors

Thaumasite formation in hydraulic mortars by atmospheric SO^ deposition

Abstract

[ES]La sulfatación de morteros y hormigones depende de las condiciones ambientales (SO^ aerosol, temperatura, etc.), así como de las características del material. Una de las fases que se puede formar como consecuencia de la sulfatación de los ligantes hidráulicos es la taumasita. En este trabajo se han expuesto diferentes morteros hidráulicos en cámaras de laboratorio con el fin de reproducir la formación de taumasita por efecto del SO^ atmosférico. Bajo las condiciones de laboratorio se formó taumasita en los morteros de cal hidráulica y en los morteros fabricados con cemento port land y cemento blanco mineralizado. Sin embargo, cuando el ligante utilizado en los morteros fue cal y puzolana, no se formó taumasita. El yeso fue el primer producto formado en la interacción entre los morteros y el SO^. A continuación, este yeso reaccionó con la calcita y el gel C-S-H dando lugar a la formación de taumasita. Las bajas temperaturas favorecieron la formación de taumasita.

[EN]Sulphation of mortars and concretes is a function of diverse environmental factors (SO^ aerosol, temperature, etc) as well as some material characteristics. One of the phases that could be formed as consequence of the sulphation of the hydraulic binder is thaumasite. In this paper different hydraulic mortars have been exposed to laboratory exposure chambers in order to reproduce thaumasite formation due to atmospheric SO^. Under the laboratory exposure conditions, thaumasite was formed in hydraulic lime mortars, and mortars elaborated with ordinary Portland cement as well as mineralized white portland cement. However, thaumasite was not formed in mortars made of lime and pozzolan. The first product formed as a result of the SO^-mortar interaction was gypsum. Gypsum reacted with calcite and C-S-H gel. present in the samples, giving place to thaumasite. Low temperature promotes thaumasite formation.

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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