A synthetic route to pyranoid epoxy-exo-glycals from D-glucose

descriptionPublicationkeyboard_double_arrow_right Article 23 Oct 2010 Spain English Publisher:ARKAT USA, Inc.Journal:Arkivoc, volume 2,011, pages 33-41 (eissn: 1551-7012,

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Authors: Gómez, Ana M.; Pedregosa, Ana; Valverde, Serafín; López Pérez, J. Cristóbal;

doi: 10.3998/ark.5550190.0012.304

handle: 10261/85641

A synthetic route to pyranoid epoxy-exo-glycals from D-glucose

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Abstract

A synthetic route to a pyranose derived epoxy-exo-glycal has been developed from D-glucose. An attempted, one-pot bromination-elimination-oxirane formation, protocol that had worked well on furanoses, resulted only in the generation of 2-bromo-C-1-methyl pyranoid glycals. © ARKAT USA, Inc.

Peer Reviewed

Country

Spain

Related Organizations

Spanish National Research Council
Spain
Instituto de Química Orgánica General
Spain

Keywords

QD241-441, Organic chemistry

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