A ferromagnetically coupled diphenoxo-bridged Gd3+–Mn2+ dinuclear complex with a large magneto-caloric effect

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2013 Spain, United Kingdom English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 49, page 3,845 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Colacio, Enrique; Ruiz, Jose; Lorusso, Giulia; Brechin, Euan K.; Evangelisti, Marco;

doi: 10.1039/c3cc41483c

pmid: 23549112

handle: 10481/95656 , 10261/85324 , 20.500.11820/78044b52-ff4d-4831-b4c1-28d4944cfebc

A ferromagnetically coupled diphenoxo-bridged Gd3+–Mn2+ dinuclear complex with a large magneto-caloric effect

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Abstract

A novel diphenoxo-bridged Gd(3+)-Mn(2+) dimer is proposed as a good candidate for cryogenic magnetic refrigeration. The large MCE is enhanced by the ferromagnetic interaction between the two metal ions.

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Spain, United Kingdom

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Keywords

/dk/atira/pure/subjectarea/asjc/2500/2508, GD, Chemistry(all), /dk/atira/pure/subjectarea/asjc/2500/2505, /dk/atira/pure/subjectarea/asjc/2500/2504, /dk/atira/pure/subjectarea/asjc/2500/2506, Metals and Alloys, LN, Catalysis, MN, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, CO, DY COMPLEXES, Materials Chemistry, Ceramics and Composites, ZN, /dk/atira/pure/subjectarea/asjc/2500/2503, /dk/atira/pure/subjectarea/asjc/1600, /dk/atira/pure/subjectarea/asjc/1500/1503

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