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Magnetic Properties of CoFe0.5Cr1.5O4 Nanoparticles

Authors: Márquez, G.; Sagredo, V.; Marquina, C.; Torres, T.E.; Ibarra, M.R.; Goya, G.F.;

Magnetic Properties of CoFe0.5Cr1.5O4 Nanoparticles

Abstract

[ES]: Nanopartículas de CoFe0:5Cr1:504 fueron sintetizadas mediante el método de auto-combustión. Las propiedades estructurales y magnéticas fueron especialmente estudiadas. Los polvos obtenidos fueron caracterizados mediante difracción de rayos-X (XRD) y medidas magnéticas en función de la temperatura y del campo magnético aplicado. El perfil de difracción de rayos-X sugiere la presencia de una sola fase cristalina correspondiente a la estructura cúbica espinela. El tamaño de las partículas fue estimado mediante la ecuación de Scherrer, obteniendo tamaños de partícula de 23 nm. La característica principal de las curvas de magnetización, Field Cooling (FC) y Zero Field Cooling (ZFC), es la presencia de una transición magnética alrededor de 175 K; por debajo de esta temperatura el compuesto se encuentra magnéticamente ordenado, en estado ferrimagnético, y por encima de 175 K el comportamiento magnético del sistema se sugiere es superparamagnético. A 5 K el óxido mixto presenta un considerable campo coercitivo de 5,8 kOe.

[EN]: Nanoparticles of CoFe0:5Cr1:504 were synthesized by using the auto-combustion method. Structural and magnetic properties were particularly investigated. The obtained powder was characterized by X-ray diffraction (XRD) and magnetic measurements as a function of temperature and applied magnetic field. X-ray diffraction data suggested the presence of single crystalline phase corresponding to cubicspinel structure. The size particle was estimated by the Scherrer equation in 23 nm. The main characteristic of the Field Cooling (FC) and Zero Field Cooling (ZFC) curves is the presence of a magnetic transition at about 175 K; below this temperature the compound is magnetically ordered, as ferrimagnetic state, and above 175 K the magnetic behavior of the system is suggested that superparamagnetic. At 5 K the mixed oxide presents a quite high coercive field, 5.8 kOe.

G. Márquez and V. Sagredo are thankful to CDCHT-ULA for providing financial support for this work through the projects: C-1641-08-05-ED and C-1658-09-05-A.

Trabajo presentado a la "Escuela Franco-Venezolana de Nanotecnología 2009 (ENANO2009)" celebrada en Caracas del 2 al 6 de noviembre de 2009.

Peer Reviewed

Country
Spain
Keywords

spinel, nanoparticles, superparamagnetism

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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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impulse
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