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handle: 10261/72237
El sistema Ar3 se ha estudiado mediante un método variacional cuántico exacto basado en la utilización de funciones Gaussianas distribuídas para describir las distancias interatómicas Ar-Ar. Este trabajo contiene el espectro de niveles rovibracionales del trímero para el caso en el que el momento angular total J sea o 0 ó 1. Para describir la rotación, se ha empleado un método aproximado,donde las autofunciones radiales del caso estrictamente vibracional, se utilizan en la resolución aproximada del problema en el que J > 0. Además de los niveles energéticos, se han calculado las correspondientes constantes rotacionales asociadas a los mismos. Dos posibles métodos para obtener dichas constantes son analizados en detalle.
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