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handle: 10261/6718
Materiales microporoso germanatos, como catalizadores. Compuestos que cristalizan en el sistema ortorrómbico. Se han obtenido por síntesis hidrotermal en un reactor revestido de teflón por reacción de una mezcla de GeO2, Cu(NO3)2.H2O o Ag(NO3), amoniaco, agua y etilenglicol, en relación molar 1:0.1:2:2:0.1, con adición de propilamina y piridina 0.3:1, para el compuesto de Cu. Estos compuestos son catalizadores para la ciclopropanación de olefinas con etil diazoacetato.
Referencia OEPM: P9900953.-- Fecha de solicitud: 07/05/1999.-- Titular: Consejo Superior de Investigaciones Científicas (CSIC).
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