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Recolector de Ciencia Abierta, RECOLECTA
Article . 2011 . Peer-reviewed
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Recolector de Ciencia Abierta, RECOLECTA
Article . 2013 . Peer-reviewed
Data sources: Recolector de Ciencia Abierta, RECOLECTA
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Triazolo[1,5-a]pyridyl phosphines reflecting the influence of phosphorus lone pair orientation on spectroscopic properties

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2011 English Publisher:Royal Society of Chemistry (UK)
Authors: Ballesteros-Garrido, R.; Bonnafoux, L.; Blanco, F.; Ballesteros, R.; Leroux, Frédérc R.; Abarca, B.; Colobert, François; +2 Authors

handle: 10261/64461

Triazolo[1,5-a]pyridyl phosphines reflecting the influence of phosphorus lone pair orientation on spectroscopic properties

Abstract

A series of new triazolopyridine-based phosphines has been prepared. These compounds revealed unexpected spectroscopic patterns. In particular, the NMR spectra are highly dependent on the relative conformational preference of the phosphine substituent at C7. Here, we report on their complete NMR analysis, X-ray structures and DFT calculations that confirm the particular arrangement of the phosphorus lone pair orbital related to the substituent pattern of the chosen phosphine. © 2011 The Royal Society of Chemistry.

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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