Trapping a Difluorocarbene–Platinum Fragment by Base Coordination

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 2010 Spain English Publisher:WileyJournal:Angewandte Chemie International Edition, volume 49, pages 4,286-4,289 (issn: 1433-7851, eissn: 1521-3773,

Copyright policy )

Authors: Martínez-Salvador, Sonia; Menjón, Babil; Forniés, Juan; Martín, Antonio; Usón, Isabel;

doi: 10.1002/anie.200907031 , 10.1002/ange.200907031

pmid: 20449859

handle: 10261/56065

Trapping a Difluorocarbene–Platinum Fragment by Base Coordination

- Summary
- Subjects
- Metrics

Abstract

Ertappt! Der Nachweis von Difluorcarben-Platin-Intermediaten bei der säureinduzierten Spaltung von Pt-CF3-Bindungen gelang durch das Abfangen einer basestabilisierten Pt--CF2-Einheit (siehe Schema). Beim Angriff eines N-Nucleophils (py*) auf das hoch elektrophile und extrem reaktive Kohlenstoffatom des Difluorcarbens wird eine C-N-Bindung gebildet.

This work was supported by the Spanish MICINN (DGPTC)/FEDER (Project CTQ2008-06669-C02-01/BQU) and the Gobierno de Aragón (Grupo de Excelencia: Química Inorgánica y de los Compuestos Organometálicos).

4 páginas, 2 figuras, 5 esquemas.

Peer reviewed

Country

Spain

Related Organizations

Spanish National Research Council
Spain
Molecular Biology Institute of Barcelona
Spain
University of Zaragoza
Spain

Keywords

Models, Molecular, Molecular Structure, Hydrolysis, Fluorine Compounds, Platin, Platinum Compounds, Metallacyclen, Carbenliganden, C-N-Kupplungen, Fluorierte liganden, Methane

Impact byBIP!

	selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	24
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Top 10%
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Top 10%