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Estudio del régimen de pérdidas dieléctricas constantes en conductores iónicos con estructura de tipo pirocloro

Authors: Díaz-Guillén, M. R.; Fuentes, A. F.; Díaz-Guillén, J. A.;

Estudio del régimen de pérdidas dieléctricas constantes en conductores iónicos con estructura de tipo pirocloro

Abstract

a temperaturas entre -20 y 250ºC y en un rango de frecuencias de 1Hz a 3MHz. Dicho estudio revela que existe un transición de una región de dependencia potencial a una región de dependencia lineal (conocida como régimen de pérdidas dieléctricas constantes o NCL) de la conductividad con la frecuencia en un amplio rango de temperaturas. Esta transición resulta estar térmicamente activada y su energía de activación ENCL es mucho menor que la energía de activación Edc para el proceso de conducción de largo alcance. Los valores de ENCL, a diferencia de Edc, son prácticamente independientes de la composición y por tanto de la concentración de vacancias de oxígeno. Por otro lado y para cada composición, los valores de ENCL= 0.67 ± 0.04 eV son muy similares a los calculados para la energía que los iones necesitan superar para salir de sus pozos de potencial, Ea= 0.69 ±0.05 eV. Los resultados obtenidos soportan la teoría que confirma que el régimen NCL es consecuencia de las vibraciones locales reflejadas en el desplazamiento cuadrático medio de los iones cuando estos permanecen confinados en su pozo de potencial.

Peer reviewed

Country
Spain
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Keywords

Conductividad, Propiedades eléctricas/dieléctricas

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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