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Catalizadores MnOx-TiO2 para la eliminación de compuestos orgánicos volátiles

Authors: Gallardo Amores, J. M.; Sánchez Escribano, V.;

Catalizadores MnOx-TiO2 para la eliminación de compuestos orgánicos volátiles

Abstract

Se han sintetizado muestras de Mn-Ti de fórmula general TixMn1-xOy (x = 0, 0.1, 0.2, 0.5, 0.8, 0.9, 1) mediante un método de coprecipitación. Las fases cristalinas mayoritarias identificadas fueron Mn3O4 (hausmanita) y TiO2 (anatasa), formándose también disoluciones sólidas a bajos porcentajes de uno de los cationes. Los materiales son estables térmicamente hasta los 873 K, tranformándose en las fases termodinámicamente estables, TiO2 (rutilo) y a-Mn2O3 a mayores temperaturas. Desde el punto de vista catalítico, son activos en la oxidación de propano y propeno, aunque el aumento del contenido de Ti parece desactivar el óxido de Mn en la oxidación de propileno. Contrariamente, en la oxidación de propano la relación Mn/Ti=1 presenta un máximo en la conversión de propano.

Peer reviewed

Keywords

VOC, disolución sólida

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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