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Boletín de la Sociedad Española de Cerámica y Vidrio
Article . 2007 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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DIGITAL.CSIC
Article . 2008 . Peer-reviewed
Data sources: DIGITAL.CSIC
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Determinación experimental y termodinámica de la influencia de la relación Al/C en la microquímica y microestructura de materiales de MgO-C-Al

Experimental and thermodynamic analysis of the Al/C ratio on the microchemistry and microstructure of MgO-C-Al materials
Authors: Serena Palomares, Sara; Sainz Trigo, M. Antonia; Caballero Cuesta, Ángel;

Determinación experimental y termodinámica de la influencia de la relación Al/C en la microquímica y microestructura de materiales de MgO-C-Al

Abstract

[ES] En el presente trabajo se ha establecido entre 1100º y 1800ºC la microquímica y microestructura de materiales de MgO-C-Al con elevado contenido en MgO y para diferentes relaciones Al/C, en condiciones fuertemente reductoras. Los resultados experimentales obtenidos se han discutido en función de la estabilidad termodinámica de las diferentes fases del sistema MgO-C-Al, determinadas teóricamente a distintas temperaturas y presiones parciales de Mg(g), Al(g) y CO (g). La combinación de ambos estudios, ha permitido realizar una descripción completa del proceso de reacción que tiene lugar en las composiciones estudiadas.

[EN] The microchemistry and microstructure of MgO-C-Al materials with high magnesia content and different Al/C ratio have been established between 1100º and 1800ºC, under strong reducing condition. The experimental results have been discussed as a function of thermodynamic stability of different phases of the MgO-C-Al system, theoretically determined at different temperatures and partial pressures of Mg(g), Al(g) and CO(g). Both studies have allowed established a complete description of the reaction process in all compositions studied.

Este trabajo ha sido financiado por el proyecto MAT-2004-04923-C02-01.

Peer reviewed

Country
Spain
Related Organizations
Keywords

Aluminio, Magnesia, Relación Al/C, graphite, aluminium, Thermodynamics stability, grafito, Clay industries. Ceramics. Glass, thermodynamics stability, aluminio, Grafito, TP785-869, Estabilidad termodinámica, Aluminium, Graphite, Al/C ratio, relación Al/C, estabilidad termodinámica, Magnesium oxide

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
Green
gold