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Article . 2024 . Peer-reviewed
License: STM Policy #29
Data sources: Crossref
https://dx.doi.org/10.48550/ar...
Article . 2024
License: arXiv Non-Exclusive Distribution
Data sources: Datacite
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Unveiling Intrinsic Bulk Photovoltaic Effect in Atomically Thin ReS2

Authors: Maria Ramos; Tanweer Ahmed; Bao Q. Tu; Eleni Chatzikyriakou; Lucía Olano-Vegas; Beatriz Martín-García; M. Reyes Calvo; +6 Authors

Unveiling Intrinsic Bulk Photovoltaic Effect in Atomically Thin ReS2

Abstract

The bulk photovoltaic effect (BPVE) offers a promising avenue to surpass the efficiency limitations of current solar cell technology. However, disentangling intrinsic and extrinsic contributions to photocurrent remains a significant challenge. Here, we fabricate high-quality, lateral devices based on atomically thin ReS2 with minimal contact resistance, providing an optimal platform for distinguishing intrinsic bulk photovoltaic signals from other extrinsic photocurrent contributions originating from interfacial effects. Our devices exhibit large bulk photovoltaic performance with intrinsic responsivities of 1 mA/W in the visible range, without the need for external tuning knobs such as strain engineering. Our experimental findings are supported by theoretical calculations. Furthermore, our approach can be extrapolated to investigate the intrinsic BPVE in other non-centrosymmetric van der Waals materials, paving the way for a new generation of efficient light-harvesting devices.

Keywords

Bulk photovoltaics, Condensed Matter - Materials Science, Broken inversion symmetry, Condensed Matter - Mesoscale and Nanoscale Physics, Intrinsic photocurrent, Mesoscale and Nanoscale Physics (cond-mat.mes-hall), Second-order conductivity, Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences

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    popularity
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    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
5
Top 10%
Average
Top 10%
Green