Characterizing the emergence of chaotic dynamics of complex networks is an essential task in nonlinear science with potential important applications in many fields such as neural control engineering, microgrid technologies, and ecological networks. Here, we solve a critical outstanding problem in this multidisciplinary research field: the emergence and persistence of spatiotemporal chaos in complex networks of damped-driven nonlinear oscillators in the significant weak-coupling regime, while they exhibit regular behavior when uncoupled. By developing a comprehensive theory with the aid of standard analytical methods, a hierarchy of lower-dimensional effective models, and extensive numerical simulations, we uncover and characterize the basic physical mechanisms concerning both heterogeneity-induced and impulse-induced emergence, enhancement, and suppression of chaos in starlike and scale-free networks of periodically driven, dissipative nonlinear oscillators.