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Thiodipropionate ZnII Complexes: Synthesis, DFT Studies, and X‐ray Structure of [{Zn(phen)(H2O)}2(μ‐tdp)2]·3H2O

Authors: Grirrane, Abdessamad; Álvarez González, Eleuterio; Pastor Navarro, Antonio; Galindo del Pozo, Agustín;

Thiodipropionate ZnII Complexes: Synthesis, DFT Studies, and X‐ray Structure of [{Zn(phen)(H2O)}2(μ‐tdp)2]·3H2O

Abstract

AbstractThe zinc thiodipropionate complex [Zn(tdp)] (1) [tdp = S(CH2CH2COO)22–] was obtained by reaction of aqueous zinc dichloride with a 1:1 mixture of Na2CO3 and thiodipropionic acid. The bonding preferences of the tdp anion were studied by DFT methods. The reaction of 1 with o‐phenanthroline (phen) gave the dinuclear compound [{Zn(phen)(H2O)}2(μ‐tdp)2]·3H2O (2), which was characterized by X‐ray analysis.

Country
Spain
Keywords

Zinc, Density functional calculations, Physical Sciences, Thiodipropionate, Coordination modes, X-ray diffraction

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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