Real-time monitoring of breathing of MIL-53(Al) by environmental SEM

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 2015 English Publisher:Elsevier BVJournal:Microporous and Mesoporous Materials, volume 203, pages 17-23 (issn: 1387-1811,

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Authors: Seoane, Beatriz; Sorribas, Sara; Mayoral, Álvaro; Téllez, Carlos; Coronas, Joaquín;

doi: 10.1016/j.micromeso.2014.10.016

handle: 10261/368999

Real-time monitoring of breathing of MIL-53(Al) by environmental SEM

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Abstract

The breathing behavior of MOF MIL-53(Al) attached to a glass support surface via covalent bonding has been monitored in real-time for a ca. one-μm single crystal with the help of environmental SEM. This allowed the attribution of porosity to the geometry in MIL-53(Al) crystals. In addition, complementary powder XRD, X-ray thermodiffractometry, TGA, Ar adsorption, FTIR, TEM and ED characterizations and crystallographic calculations were in agreement with the previous related literature.

Financial support (MAT2010-15870, MAT2013-40556-R) and FPU Program fellowships (B. S.) from the Spanish MINECO, the Aragón Government and the ESF are gratefully acknowledged. We acknowledge the use Servicio General de Apoyo a la Investigación-SAI (Universidad de Zaragoza).

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University of Zaragoza
Spain

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