Unusual fragmentation of CH2Cl2by an Ir(iii) centre bonded to a doubly metalated TpMsLigand (TpMs= hydrotris(3-mesitylpyrazol-1-yl)borate)

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2006 Spain English Publisher:Royal Society of Chemistry (RSC)Journal:Chem. Commun. (issn: 1359-7345, eissn: 1364-548X,

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Authors: López, Jorge A.; Mereiter, Kurt; Paneque, Margarita; Poveda, Manuel L.; Serrano, Oracio; Trofimenko, Swiatoslaw; Carmona, Ernesto;

doi: 10.1039/b608293a

pmid: 17268671

handle: 10261/36363

Unusual fragmentation of CH2Cl2by an Ir(iii) centre bonded to a doubly metalated TpMsLigand (TpMs= hydrotris(3-mesitylpyrazol-1-yl)borate)

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Abstract

The Ir(III) compound Tp(Ms'')Ir(N2), that contains a pentadentate, doubly metalated 3-mesityl substituted tris(pyrazolyl)borate ligand, induces the cleavage of C-H and C-Cl bonds of CH2Cl2 to yield a highly electrophilic chlorocarbene Ir=C(H)Cl complex.

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Keywords

TpMs"Ir(N2), Borates, IrC(H)CI, 3-mesitylpyrazol-1-yl, Pentadentate, CH2Cl2

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