Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2010 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 46, page 8,851 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Melero, Cristóbal; Martínez-Prieto, Luis Miguel; Palma, Pilar; Río, Diego del; Álvarez, Eleuterio; Cámpora, Juan;

doi: 10.1039/c0cc02972f

pmid: 20967320

handle: 10261/36294

Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species

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Abstract

Well-defined dimeric or polymeric Pd(0) complexes [Pd(μ-(iPr)PCHP)](n) (n = 2 or ∞) containing the bridging ligand α,α'-bis(diisopropylphosphino)-m-xylene ((iPr)PCHP) are produced under mild conditions when the cyclometallated PCP pincer complex ((iPr)PCP)Pd-OH reacts with methanol or isopropanol.

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Keywords

Models, Molecular, Molecular Structure, Methanol, Pd(0), Isopropanol, Crystallography, X-Ray, Ligands, PCP, Dimeric, 2-Propanol, Cyclometallated, Organometallic Compounds, Pd, Polymeric, Oxidation-Reduction, Palladium

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