
handle: 10261/35688
[ESP]En el borde SW de la Cuenca del Duero (Meseta Central Española) hay importantes masas opalinas constituídas por rocas sedimentarias silicificadas que pueden ser activas con cal (reacción puzzolánica). Estas sustancias opalinas contienen sílice bajo diversas formas, con diferente reactividad respecto a la cal. El estudio de mezclas diferentes de roca opalinaical a diferentes edades indica que el ópalo-A es el más activo, originando inicialmente silicatos mal cristalizados de baja relación CaíSi que evolucionan luego a robermorita durante el proceso de endurecimiento. Se propone un mecanismo de reacción para este proceso. Dado que rocas análogas a las consideradas se han citado en otras partes del mundo deficirarias en materiales puzzolánicos, sin que se tenga noticia de que hayan sido explotadas como materiales para la constmcción, este estudio puede ser de utilidad muy general.
[ENG] On the SW border of the Dueto basin (Central Plateau of Spain) there are important opaline masses formed of silicified sedimentary rocks that can become activated by addition of lime (puzzolanic reaction). These opaline substances contain silica in different forms, with a different reaction to the presence of lime. Study of opaline rockilime mixtures of several ages shows that opal-A is the most active, initially originating poorly crystallized silicates with a low CaISi reaction that later evolve to tobermorite during the hardening process. A reaction mechanism for this process is proposed. Since rocks similar to those considered are well know without they have been used as construction materials, the present study could be of general interest.
Los autores agradecen a la Caja de Ahorros de Salamanca y Soria su ayuda económica. Esta investigación es una contribución al proyecto PR84-0159-CO3-01 de la CAICYT.
Peer reviewed
12 p.
Reactividad opalina, Endurecimiento, Mecanismo Cinético, C-S-H,
Reactividad opalina, Endurecimiento, Mecanismo Cinético, C-S-H,
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