Conformational control enables boroxine-to-boronate cage metamorphosis

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2023 Spain English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Science, volume 14, pages 12,953-12,960 (issn: 2041-6520, eissn: 2041-6539,

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Authors: Manuel Rondelli; Samuel Delgado-Hernández; Antonio H. Daranas; Tomás Martín;

doi: 10.1039/d3sc02920d

pmid: 38023528

pmc: PMC10664459

handle: 10261/337176

Conformational control enables boroxine-to-boronate cage metamorphosis

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Abstract

The conformational control of boronic acid building blocks allows efficient self-assembly into a tetrahedral boroxine cage. The nano-sized cage displays molecular metamorphosis, converting from a boroxine tetrapod to a boronate bipyramid.

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Spain

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Keywords

Chemistry, Conformational control, boroxine-toboronate cage metamorphosis

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