Influence of the contact model and support characteristics on the partition constant for kinetically controlled synthesis of peptides

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1989 Spain English Publisher:WileyJournal:Journal of Chemical Technology & Biotechnology, volume 45, pages 271-278 (issn: 0268-2575, eissn: 1097-4660,

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Authors: Clapés Saborit, Pere; Mata-Álvarez, Joan; Valencia Parera, Gregorio; Reig Isart, Francisca; Haro Villar, Isabel; García-Antón, José María;

doi: 10.1002/jctb.280450404

handle: 10261/331887

Influence of the contact model and support characteristics on the partition constant for kinetically controlled synthesis of peptides

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Abstract

AbstractThe influence of the physical characteristics of the support and the contact model on the partition constant (p) in kinetically controlled peptide synthesis was studied. Large values for p were obtained using a small pore size carrier and a recirculation reactor. However, with a larger pore size carrier and the same contact model, p values were lower, the latter conditions were more favorable for product synthesis.

Country

Spain

Related Organizations

University of Barcelona
Spain
Spanish National Research Council
Spain

Keywords

Organic solvents, Immobilization, Diatomaceous earth, Partition constant, Recirculation reactor, Enzymatic peptide synthesis, α‐chymotrypsin

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