Inversion of chirality in GTM-4 enantio-enriched zeolite driven by a minor change of the structure-directing agent

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2022 Spain, Spain English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 58, pages 13,083-13,086 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Ramón de la Serna; Itziar Arnaiz; Carlos Márquez-Álvarez; Joaquín Pérez-Pariente; Luis Gómez-Hortigüela;

doi: 10.1039/d2cc04958a

pmid: 36349553

handle: 10261/304466

Inversion of chirality in GTM-4 enantio-enriched zeolite driven by a minor change of the structure-directing agent

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Abstract

The replacement of an ethyl by a benzyl substituent in N-methyl-pseudoephedrine-derived chiral SDAs brings an astonishing inversion of chirality in the resulting -ITV zeolite framework, also leading to an increase of the enantioselective properties.

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