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Process for preparing mesoporous silicates containing ti and organic compounds directly linked to network atoms, and use thereof as catalyst.

Authors: Navarro, María Teresa; Corma, Avelino; Jordá Moret, José Luis; Rey García, Fernando;

Process for preparing mesoporous silicates containing ti and organic compounds directly linked to network atoms, and use thereof as catalyst.

Abstract

[EN]The invention relates to a process for producing micro and mesoporous silicates which contain elements with a valence of 2, 3 and 4 such as Ge, Ti, Al, B, Ga, Cr, Fe, Zn, V and combinations thereof, and organic groups which are directly linked to network atoms. These catalysts are highly active and selective for reactions of selective oxidation of organic compounds with organic or inorganic peroxides. Hence, they can be used as acid catalysts when they contain trivalent elements in their composition. [ES] La presente invención describe un método para la obtencion de silicatos micro y mesoporosos conteniendo elementos de valencia 2,3 y 4, tales como Ge, Ti, Al, B, Ge, Ga, Cr, Fe, Zn, V, y combinaciones de ellos, y grupos orgánicos directamente unidos a átomos de la red. Estos catalizadores son altamente activos y selectivos para reacciones de oxidacion selectiva de compuestos orgánicos con peróxidos orgánicos o inorgánicos. Asimismo, pueden ser empleados como catalizadores ácidos en el caso en que contengan elementos trivalentes en su composición.

Fecha de solicitud:2.08.1999.- Titular:Consejo Superior de Investigaciones Cietíficas (CSIC).- Universidad Politecnica de valencia.

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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