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handle: 10261/29656
[EN]The invention relates to a process for producing micro and mesoporous silicates which contain elements with a valence of 2, 3 and 4 such as Ge, Ti, Al, B, Ga, Cr, Fe, Zn, V and combinations thereof, and organic groups which are directly linked to network atoms. These catalysts are highly active and selective for reactions of selective oxidation of organic compounds with organic or inorganic peroxides. Hence, they can be used as acid catalysts when they contain trivalent elements in their composition. [ES] La presente invención describe un método para la obtencion de silicatos micro y mesoporosos conteniendo elementos de valencia 2,3 y 4, tales como Ge, Ti, Al, B, Ge, Ga, Cr, Fe, Zn, V, y combinaciones de ellos, y grupos orgánicos directamente unidos a átomos de la red. Estos catalizadores son altamente activos y selectivos para reacciones de oxidacion selectiva de compuestos orgánicos con peróxidos orgánicos o inorgánicos. Asimismo, pueden ser empleados como catalizadores ácidos en el caso en que contengan elementos trivalentes en su composición.
Fecha de solicitud:2.08.1999.- Titular:Consejo Superior de Investigaciones Cietíficas (CSIC).- Universidad Politecnica de valencia.
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