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handle: 10261/296172
[ES] Se propone un método analítico para la determinación de ión calcio en agua de mar, por valoración volumétrica, con detección potenciométrica del punto final mediante electrodo selectivo al ion calcio, usando el agente complejante EGTA (ácido etilenglicol-bis- (2-aminoetileter)-N, N, N', N', tetraacético), que hace mínima la interferencia con otros iones alcalinotérreos. La cantidad de bórax añadido resulta óptima para tamponar el pH durante la titulación. El método se aplicó al estudio de dos cortes realizados en la Ría de Arosa, durante la campaña oceanográfica GALICIA X. La reproducibilidad obtenida fue de 0,04%, superior a la obtenida en otros métodos con punto final potenciométrico o con indicadores colorimétricos
[EN] An analytical method for the determination of calcium ion in seawater is proposed, by volumetric titration with potentiometric detection of end-point by calcium ion selective electrode, using EGTA (ethyleneglycol-bis (B-aminoethylether), N, N, N', N’, tetraacetic acid) as a titrant, which produces least interference with other alkaline ions. The ammount of added borax is eminently good for buffering the pH during the titration. The method was applied to the study of two legs performed in Ria de Arosa, during the cruise GALICIA X. A reproductibility of 0.04% was obtained, better than other methods with potentiometric end-point or colorimetric indicators
8 pages, 6 figures, 2 tables.-- V Seminario de Química Marina, Cádiz, 23-24 enero 1990
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