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Revista geológica de Chile
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Mineralogía y geoquímica de las micas en las pegmatitas Santa Elena y El Peñón, Provincia Pegmatítica Pampeana, Argentina

Authors: Galliski, Miguel A.; Saavedra, Julio; Márquez-Zavalía, María F.;

Mineralogía y geoquímica de las micas en las pegmatitas Santa Elena y El Peñón, Provincia Pegmatítica Pampeana, Argentina

Abstract

{ESP}Se estudiaron las propiedades físicas y ópticas, los politipos, la composición química y la paragénesis de las micas de las pegmatitas de elementos raros Santa Elena y El Peñón. La primera es de tipo complejo, subtipo petalita y la segunda de tipo berilo subtipo berilo-columbita-fosfato: ambas pertenecen al distrito El Quemado, el más septentrional de la Provincia Pegmatítica Pampeana. Las micas son muscovitas, muscovitas litíferas, formas intermedias y lepidolitas. Las muscovitas s.I. tienen estructura 2 M, y una composición con bajos contenidos de Mn, Li, Rb, Cs, Tl e Y, un espécimen puede ser clasificado como 'muscovita rosa'. Las lepidolitas s.I. tienen estructuras del politipo 2 M, más algunas difracciones del politipo 1 M o 2 M, y comprenden algunas micas dioctaédricas y otras trioctaédricas. Son más ricas en SiO2, MnO, CaO, Li2O, Rb2O, Cs, Tl, Y y P que las muscovitas. La evolución geoquímica de las micas muestra una tendencia general con relaciones K/Rb decrecientes con la diferenciación y correlación negativa de esta relación con los contenidos de cesio, talio, itrio, litio y manganeso, en algunos casos (itrio) prácticamente lineal. Las micas litíferas de la pegmatita de subtipo petalita habrían cristalizado aproximadamente a una P de 2 a 3 kbar y a 350-400ºC, en el campo de estabilidad de espodumeno, bajo un incremento de la actividad ( ) HF, KF y LiF. Las micas de la pegmatita de subtipo berilo-columbita-fosfato habrían cristalizado en el mismo rango de P y T un poco más alta, de una fracción pobre en litio cosanguínea, pero no comagmática, con la que originó la pegmatita litífera.

{ENG}This study describes the physical and optical properties, polytypism, chemical composition and paragenesis of a Li-Al-bearing mica suite from the northernmost pegmatite field of Pampean Pegmatite Province. The micas are from two possible cogenetic rare-element pegmatites: Santa Elena, a complex-type, petalite subtype pegmatite, and El Peñón, a beryl-type, beryl-columbite-phosphate subtype pegmatite. The micas are muscovite, lithian muscovite, mixed forms and lepidolite. The muscovite s.I. has 2 M, structure and chemistry with comparatively low contents of Mn, Li, Rb, Cs, Ti and Y; one specimen could be classified as a 'rose muscovite'. The lepidolite and mixed forms have 2 M, dominant polytypism with some scarce X-ray reflections of 1 M or 2 M, polytypes. They are higher in SiO2, MnO, CaO, Li2O, Rb2O, Cs, Ti, Y and P. Li2O ranges between 3,71 and 4,73%, and Rb2O from 0,29 to 2,53%. The geochemical evolution of the micas, illustrated by K/Rb versus lithium, manganeso, cesium, thallium and ytrium diagrams, shows a differentiation trend similar to micas from other LCT pegmatite fieids. The inferred crystallization path has evolved approximately around 2-3 kbar and 350-400ºC, in the stability field of spodumene, in a H2O-saturated environment, under increasing HF, KF and LiF activities.

Country
Spain
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Keywords

Argentina, Micas, Mineralogy, Míneralogy, Geochemístry, Geochemistry, Geoquímica, Pegmatites, Argentia, Pegmatitas, Mineralogía

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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