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Microporous crystalline material of zeolitic nature, zeolite ITQ-39, method of preparation and uses

Authors: Corma, Avelino; Moliner Marín, Manuel; Rey García, Fernando; González González, Jorge;

Microporous crystalline material of zeolitic nature, zeolite ITQ-39, method of preparation and uses

Abstract

Las preocupaciones de la presente invención un material cristalino microporoso de la naturaleza zeolítica, ITQ-39, caracterizado en que tiene, adentro calcinated a estado y en la ausencia de fallos, demostrada por la presencia de silanoles, en la red cristalina de eso, la fórmula empírica: 5 x (M 1/n XO 2): y YO 2: ¿SiO 2 en donde M se selecciona de H , un catión inorgánico de la carga de +n, y una mezcla de ambos, X es por lo menos un elemento del producto químico del estado de oxidación +3, Y es por lo menos un elemento del producto químico con el estado de oxidación +4 diferente del silicio, 10 x tiene un valor entre 0 y 0.3, incluido, y tiene un valor entre 0 y 0.1, ambo incluido, y porque el material de tipo, en el estado sintetizado, tiene un diagrama de difracción de la radiografía con, por lo menos, los valores del ángulo 2? (niveles) y intensidades relativas (I/I 0) mostradas en Tabla I, el método de preparación de eso y el uso de eso en procedimientos de la transformación, de la absorción y de la separación de compuestos orgánicos.

The present invention concerns a microporous crystalline material of zeolitic nature, ITQ-39, characterised in that it has, in calcinated state and in absence of faults, demonstrated by the presence of silanols, in the crystalline network thereof, the empirical formula: 5 x (M 1/n XO 2 ) : y YO 2 : SiO 2 wherein M is selected from H , an inorganic cation of +n charge, and a mixture of both, X is at least a chemical element of oxidation state +3, Y is at least a chemical element with oxidation state +4 different from Si, 10 x takes a value between 0 and 0.3, both inclusive,y takes a value between 0 and 0.1, both inclusive, and because the material, in synthesised state, has an X-ray diffraction pattern with, at least, the values of angle 2? (degrees) and relative intensities (I/I 0 ) shown in table I, method of preparation thereof and use thereof in processes of transformation, absorption and separation of organic compounds.

Consejo Superior de Investigaciones Científicas (España), Universidad Politecnica de Valencia

Fecha de solicitud: 07-08-2008.

Peer reviewed

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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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