Synthesis and characterization of an unusual tetranuclear rhodium complex; X-ray molecular structure of [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2](az = 7-azaindolate; nbd = norborna-2,5-diene)

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1984 English Publisher:Royal Society of Chemistry (RSC)Journal:J. Chem. Soc., Chem. Commun. (issn: 0022-4936,

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Authors: Oro, Luis A.; Ciriano, Miguel A.; Villarroya, B. Eva; Tiripicchio, Antonio; Lahoz, Fernando J.;

doi: 10.1039/c39840000521

handle: 10261/272567

Synthesis and characterization of an unusual tetranuclear rhodium complex; X-ray molecular structure of [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2](az = 7-azaindolate; nbd = norborna-2,5-diene)

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Abstract

The complex [RhCl(nbd)(Haz)](nbd = norborna-2,5-diene, Haz = 7-azaindole) reacts with [Rh(acac)(CO)2](acac = MeCOCHCOMe) to give the tetranuclear compound [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2], whose structure, determined by an X-ray analysis, contains a novel planar Rh4Cl2framework and two directly bonded rhodium atoms with different electronic environments. Peer reviewed

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