Regioselective Addition of PRPh2 to the Cα Atom of the Diphenylallenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PPri3)]BF4

descriptionPublicationkeyboard_double_arrow_right Article 31 Oct 1998 English Publisher:American Chemical Society (ACS)Journal:Organometallics, volume 17, pages 5,434-5,436 (issn: 0276-7333, eissn: 1520-6041,

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Authors: Esteruelas, Miguel A.; Gómez, Angel V.; López, Ana M.; Modrego, Francisco J.; Oñate, Enrique;

doi: 10.1021/om980577d

handle: 10261/272363

Regioselective Addition of PRPh2 to the Cα Atom of the Diphenylallenylidene Ligand of [Ru(η5-C5H5)(CCCPh2)(CO)(PPri3)]BF4

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Abstract

The allenylidene ligand of [Ru(η5-C5H5){CCCPh2}(CO)(PPri3)]BF4 adds PHPh2, PMePh2, and PPh3 selectively at the Cα atom, whereas OH- and [OMe]- are added at the Cγ atom. We thank the DGES (Project PB-95-0806, Programa de Promoción General del Conocimiento) for financial support. Peer reviewed

Related Organizations

University of Zaragoza
Spain
Spanish National Research Council
Spain

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