Electronic structure and geometries of o-carborane derived cyclic structures [{μ-1,2-(C2B10H10)nMn}Agm]z−, M = {Au, Hg}, n = {3, 4}, m = {0, 1, 2}, z = {n − m, −m}

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2012 Spain English Publisher:Royal Society of Chemistry (RSC)Journal:Dalton Transactions, volume 41, page 14,146 (issn: 1477-9226, eissn: 1477-9234,

Copyright policy )Funded by:EC | LIMA

Authors: Aullón, Gabriel; Laguna, Antonio; Oliva, José M.;

doi: 10.1039/c2dt31047c

pmid: 23032998

handle: 10261/271593

Electronic structure and geometries of o-carborane derived cyclic structures [{μ-1,2-(C2B10H10)nMn}Agm]z−, M = {Au, Hg}, n = {3, 4}, m = {0, 1, 2}, z = {n − m, −m}

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Abstract

To date, crystal structures of the cyclic mercury complexes [μ-1,2-(C(2)B(10)H(10))(n)Hg(n)], with n = {3, 4}, have been found. However, the same structures substituting Hg by Au, which implies a charge z = {-3, -4} for n = {3, 4} respectively, have not been found. In this work, we present geometrical and electronic structure properties of the title structures [μ-1,2-(C(2)B(10)H(10))(n)M(n)](z-), M = {Au, Hg}, n = {3, 4}, z = {n, 0}, and study the stability of structures with one and two added Ag(+) ions.

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Spain

Related Organizations

Spanish National Research Council
Spain
Institute of Physical Chemistry "Rocasolano"
Spain
University of Zaragoza
Spain
University of Barcelona
Spain

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