This paper reports the values of the standard (p∘=0.1 MPa) molar enthalpy of formation in the condensed, at T=298.15 K, for 2-R-benzimidazoles (R=propyl, isopropyl), derived from, the respective enthalpies of combustion in oxygen, measured by static bomb combustion calorimetry and the standard molar enthalpies of sublimation, at T=298.15 K, obtained using Calvet microcalorimetry in the case of 2-isopropylbenzimidazole and, by the variation of vapour pressures, determined by the Knudsen effusion technique, with temperatures between (344 and 365) K for 2-propylbenzimidazole. Heat capacities, in the temperature ranges from T=268 K to near their respective melting temperatures, T=421 K for 2-propylbenzimidazole and T=464 K for 2-isopropylbenzimidazole, were measured with a differential scanning calorimeter. These values were used to derive the standard molar enthalpies of formation, of the two 2-benzimidazole derivatives, in gaseous phase. Thanks are due to Instituto de Cooperação Cientı́fica e Tecnológica Industrial (ICCTI), Lisbon, Portugal, and Consejo Superior de Investigaciones Cientı́ficas (CSIC), Madrid, Spain for a joint research project CSIC/ICCTI; M.L.P.F.A. thanks Fundação para a Ciência e Tecnologia (FCT), Lisbon, Portugal, for the award of a postdoctoral fellowship (SRFH/BPD/5595/2001). The Spanish DGI/MCyT is acknowledged under projects BQU2000-0252, 0906 and 1497; M.T. thanks MECD/SEEU, AP2002-0603, Spain for financial support.