A mild, efficient and selective oxidation of sulfides to sulfoxides

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1998 Spain Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Fraile, José M.; Lázaro, Beatriz; Mayoral, José A.;

doi: 10.1039/a804180f

handle: 10261/270943

A mild, efficient and selective oxidation of sulfides to sulfoxides

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Abstract

Several titanium derivatives supported on silica have been investigated as catalysts in the sulfide→sulfoxide oxidation; the supported titanium/tartaric acid catalyst is highly suited to reactions carried out with H2O2, leading to high yields and high sulfoxide/sulfone selectivities, while small asymmetric inductions (up to 13%) are observed.

This work was made possible by the generous financial support of the C.I.C.Y.T. (Project MAT96-1053).

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Spain

Related Organizations

Spanish National Research Council
Spain

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