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handle: 10261/265184 , 11441/131013
It is demonstrated that, besides classical nanocolumnar arrays, the oblique angle geometry induces the growth of singular structures in the nanoscale when using wisely designed patterned substrates. Well-ordered array of crosses, cylindrical nanorods or hole structures arranged in square or hexagonal regular geometries are reported as examples, among others. The fundamental framework connecting substrate topography and film growth at oblique angles is presented, allowing the use of substrate patterning as a feasible thin film nanostructuring technique. A systematic analysis of the growth of TiO2 thin films on 4 different lithographic patterned substrates in 4 different scale lengths is also presented. A first conclusion is the existence of a height-based selective growth in the initial stages of the deposition, by which the film preferentially develops on top of the tallest substrate features. This behavior is maintained until the film reaches a critical thickness, the so-called Oblivion Thickness, above which the film topography becomes gradually independent of the substrate features. A general formula relating the spatial features of the pattern, the coarsening exponent and the Oblivion Thickness has been deduced. MCIN/AEI/and FEDER project PID2019-110430GB-C21 MCIN/AEI/ and FEDER project PID2020-112620GB-I00 MCIN/AEI/ and FEDER project PID2020-114270RA-I00 MCIN/AEI/ and FEDER project RTI2018-098117-B-C21 Junta de Andalucía PAIDI-2020 project P18-RT-3480 Junta de Andalucía PAIDI-2020 project P18-RT-6079 University of Seville VI PPIT-US
Substrate patterning, Oblique angle deposition, Porous thin films, Nanostructured thin films, Magnetron sputtering
Substrate patterning, Oblique angle deposition, Porous thin films, Nanostructured thin films, Magnetron sputtering
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