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Direct Evidence of a Graded Magnetic Interface in Bimagnetic Core/Shell Nanoparticles Using Electron Magnetic Circular Dichroism (EMCD)

Authors: Daniel del-Pozo-Bueno; María Varela; Marta Estrader; Alberto López-Ortega; Alejandro G. Roca; Josep Nogués; Francesca Peiró; +1 Authors

Direct Evidence of a Graded Magnetic Interface in Bimagnetic Core/Shell Nanoparticles Using Electron Magnetic Circular Dichroism (EMCD)

Abstract

Interfaces play a crucial role in composite magnetic materials and particularly in bimagnetic core/shell nanoparticles. However, resolving the microscopic magnetic structure of these nanoparticles is rather complex. Here, we investigate the local magnetization of antiferromagnetic/ferrimagnetic FeO/Fe3O4 core/shell nanocubes by electron magnetic circular dichroism (EMCD). The electron energy-loss spectroscopy (EELS) compositional analysis of the samples shows the presence of an oxidation gradient at the interface between the FeO core and the Fe3O4 shell. The EMCD measurements show that the nanoparticles are composed of four different zones with distinct magnetic moment in a concentric, onion-type, structure. These magnetic areas correlate spatially with the oxidation and composition gradient with the magnetic moment being largest at the surface and decreasing toward the core. The results show that the combination of EELS compositional mapping and EMCD can provide very valuable information on the inner magnetic structure and its correlation to the microstructure of magnetic nanoparticles.

Country
Spain
Keywords

EMCD, Nanocubes, EELS, Nanopartícules, Interfaces, Magnetic Nanoparticles, Circular dichroism, Core/Shell Nanoparticles, Oxidation state, Graded interfaces, Materials magnètics, Magnetic nanoparticles, Nanoparticles, Core/shell nanoparticles, Graded Interfaces, Electron energy loss spectroscopy, Dicroisme circular, Magnetic materials

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
OpenAIRE UsageCountsViews provided by UsageCounts
downloads
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18
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104
132
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