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The Journal of Physical Chemistry A
Article . 2002 . Peer-reviewed
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Anisotropic Distributions of Ion Fragments Produced by Dissociative Ionization of Halogenated Ethylenes in Intense Laser Fields

Authors: Castillejo, Marta; Martín Muñoz, Margarita; de Nalda, R.; Couris, Stelios; Koudoumas, E.;

Anisotropic Distributions of Ion Fragments Produced by Dissociative Ionization of Halogenated Ethylenes in Intense Laser Fields

Abstract

The angular distributions of fragments arising from dissociative ionization of chloroethylene (H2CCHCl), bromoethylene (H2CCHBr), and 2-chloroethenylsilane (H3SiHCCHCl) by a linearly polarized pulsed laser field (800 nm, 50 fs, 2 × 1014 W cm-2) have been measured using a time-of-flight mass spectrometer. The angular distributions of the multiply charged halogen and silicon ions originating from different molecules are markedly anisotropic, yielding a maximum signal for a laser polarization along the axis of the time-of-flight detector. In contrast, the anisotropy of the distributions of the multiply charged carbon ions depends on the parent molecule: for chloroethylene and bromoethylene they are peaked preferentially in the direction parallel to the laser polarization, for 2-chloroethenylsilane they are peaked perpendicular to it. The anisotropy of all the above distributions is found to increase with the charge multiplicity of the ion fragment. The fragment anisotropies are discussed in terms of the molecular alignment, due to the nonresonant polarizability interaction, and of the selection of orientation in the ionization and dissociation dynamics in the strong laser field. This research has benefited from support from Project PB96-0844-C02-01 (DGICYT Spain).

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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