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Journal of Synchrotron Radiation
Article . 2008 . Peer-reviewed
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Bradford Scholars
Article . 2008
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Simultaneous birefringence, small- and wide-angle X-ray scattering to detect precursors and characterize morphology development during flow-induced crystallization of polymers

Authors: Fernandez-Ballester, L.; Gough, Tim; Meneau, F.; Bras, W.; Ania, F.; Balta-Calleja, F.J.; Kornfield, J.A.;

Simultaneous birefringence, small- and wide-angle X-ray scattering to detect precursors and characterize morphology development during flow-induced crystallization of polymers

Abstract

An experimental configuration that combines the powerful capabilities of a short-term shearing apparatus with simultaneous optical and X-ray scattering techniques is demonstrated, connecting the earliest events that occur during shear-induced crystallization of a polymer melt with the subsequent kinetics and morphology development. Oriented precursors are at the heart of the great effects that flow can produce on polymer crystallization (strongly enhanced kinetics and formation of highly oriented crystallites), and their creation is highly dependent on material properties and the level of stress applied. The sensitivity of rheo-optics enables the detection of these dilute shear-induced precursors as they form during flow, before X-ray techniques are able to reveal them. Then, as crystallization occurs from these precursors, X-ray scattering allows detailed quantification of the characteristics and kinetics of growth of the crystallites nucleated by the flow-induced precursors. This simultaneous combination of techniques allows unambiguous correlation between the early events that occur during shear and the evolution of crystallization after flow has stopped, eliminating uncertainties that result from the extreme sensitivity of flow-induced crystallization to small changes in the imposed stress and the material. Experimental data on a bimodal blend of isotactic polypropylenes are presented.

Countries
United Kingdom, United States
Keywords

Birefringence, birefringence, Mechanical Engineering, polymer, WAXD, flow-induced crystallization, Simultaneous. Optical. SAXS. WAXD. Flow induced crystallization. Polymer. Birefringence., simultaneous, SAXS, 540, 530, optical, REF 2014, Flow-induced crystallisation, Polymer, Simultaneous, Optical

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
OpenAIRE UsageCountsViews provided by UsageCounts
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22
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