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handle: 10261/23831
Se realiza el reagrupamiento de Claisen de la 4-alil-oxi-cumarina y de la 4-(dimetilalil-oxi)-cumarina en distintas condiciones experimentales. Se aíslan e identifican cinco derivados reagrupados. Se discuten los resultados y se hacen algunas aportaciones al estudio de los mecanismos de estos reagrupamientos.
Claisen rearrangement of 4-allyl-oxy-coumarin and 4-(3',3'-dimethyl-allyl-oxy)-coumarin was carried out in different experimental conditions. Five rearrangement derivatives were isolated and identified. The resultas are discussed and contributions to the Claisen rearrangement mechanism are presented
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