Síntesis de cumarinas. IV. Productos de transposición de la 7-(3,'3'-dimetilaliloxi)-cumarina
González, A. G.; López Dorta, H.; Medina Medina, M. C.; Rodríguez Luis, F.;
Síntesis de cumarinas. IV. Productos de transposición de la 7-(3,'3'-dimetilaliloxi)-cumarina
by rearrangement from 7-(3',3'-dimethylaliloxy)-coumarin, at several temperatures, in DMA solution, 6-(1',2'-dimethylallyl)-7-hydroxycoumarin, 6-(1',1'-dimethylallyl)-7-hydroxycoumarin, 8-(1',2'-dimethylallyl)-7-hydroxycoumarin, 2',3,3'-trimethyl-2',3'-dihydroangelicin and 2',2',3'-trimethyl-2',3'-angelicin, have been obtained.
Por transposición de la 7-(3',3'-dimetilaliloxi)-cimarina, en DMA a diferentes temperaturas, se han obtenido 6-(1',2'-dimetilalil)-7-hidroxicumarina, 6- 1',1'-dimetilali)-7-hidroxicumarina, 8-(1',2'-dimetilalil)-7-hidroxicumarina, 2',3',3'-trimetil-2',3'-dihidroangelicina y 2',2',3'-trimetil-2',3'-dihidroangelicina.
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