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handle: 10261/229800
The present invention relates to a hybrid material comprising a copper and nickel MOF with oxamate ligands Ni2 II{NiII 4[CuII 2(Me3mpba)2]3}-54H2O (NiII@MOF) containing subnanometer metal clusters, preferably with less than 7 atoms, confined in the channels of the MOF. The invention also relates to the production method thereof and to the use of same as a catalyst in the formation of compounds with higher added value, e.g. cycloheptatrienes. [EN]
La presente invención se refiere a un material híbrido que comprende un MOF de cobre y níquel con ligandos oxamato Ni2 II{NiII 4[CuII 2(Me3mpba)2]3}-54H2O (NiII@MOF) que contiene clústeres metálicos subnanometricos, preferentemente de menos de 7 átomos, confinados en los canales del MOF, a su procedimiento de obtención y a su uso como catalizador en la formación de compuestos de mayor valor añadido, por ejemplo cicloheptatrienos. [ES]
Universitat de València, Universitat Politècnica de València, Consejo Superior de Investigaciones Científicas (España)
A1 Solicitud de patente con informe sobre el estado de la técnica
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