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Regioselective, stereoselective and catalytic hydrochlorination of alkynes

Authors: Corma, Avelino; Leyva, Antonio; Oliver Meseguer, Judit;

Regioselective, stereoselective and catalytic hydrochlorination of alkynes

Abstract

La presente invención describe un procedimiento de obtención de cloruros de vinilo que puede comprender, al menos, las siguientes etapas: - Una primera etapa en la que, al menos, un alquino seleccionado entre acetileno, un derivado del acetileno y combinaciones de los mismos, y cloruro de hidrógeno se pone en contacto con un catalizador que contiene, al menos, nanopartículas de oro en presencia de un aditivo polar no prótico. - Una segunda etapa de calentamiento de la mezcla obtenida. - Una tercera etapa de recuperación del producto. [ES]

The invention relates to a method for producing vinyl chlorides which can comprise at least the following steps: a first step in which at least one alkyne selected from acetylene, an acetylene derivative and combinations thereof, and hydrogen chloride are placed in contact with a catalyst containing at least gold nanoparticles in the presence of an aprotic polar additive; a second step of heating the obtained mixture; a third step of recovering the product. [EN]

Consejo Superior de Investigaciones Científicas (CSIC), Universitat Politècnica de València

A1 Solicitud de patente con informe sobre el estado de la técnica

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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