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handle: 10261/223224
[DE]: Die Reaktion von Zirkon mit Aluminiumoxid bei 1600°C wurde mit einem durch Schlickerguß hergestellten Zirkon-Aluminiumoxid Vielschicht-Verbund untersucht. Dabei hat sich gezeigt, daß sich in der ersten Stufe der Reaktion das Zirkon in einer silikatreichen Glasphase löst und sich danach ZrO2 und Mullit ausscheidet. Auf den Einfluß der im Zirkonpulver immer vorhandenen Verunreinigungen wird ebenso eingegangen.
[EN]: The mechanism of the zircon-alumina reaction at 1600°C has been studied using a zircon-alumina multilayer composite obtained by slip casting. It has been found that in the first stage of the reaction the zircon is dissolved in a silica-rich glassy phase with the subsequent precipitation of zirconia and mullite. The role of impurities always present in the zircon powder is also discussed.
[FR]: On a étudié le mécanisme de la réaction ZrSiO4-Al2O3 à 1600°C en utilisant un composite multicouche de ZrSiO4-Al2O3 obtenu par coulage. On a établi que, dans la première étape de la réaction, ZrSiO4 se dissous dans une phase vitreuse et qu'ensuite de la zircone et de la mullite précipitent. On discute également du rôle des impuretés toujours présentes dans la poudre de ZrSiO4.
One of us (J. S. Moya) thank NATO for the concession of a grant. This work was supported by EC-EURAM Project Contract No. MAlE/OO58/C.
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