Fructose dehydration reaction over functionalized nanographitic catalysts in MIBK/H2O biphasic system

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 2021 Spain English Publisher:Elsevier BVJournal:Catalysis Today, volume 366, pages 68-76 (issn: 0920-5861,

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Authors: Gabriel Delgado Martin; Charf Eddine Bounoukta; Fatima Ammari; María Isabel Domínguez; Antonio Monzón; Svetlana Ivanova; Miguel Ángel Centeno;

doi: 10.1016/j.cattod.2020.03.016

handle: 11441/140623 , 10261/220886

Fructose dehydration reaction over functionalized nanographitic catalysts in MIBK/H2O biphasic system

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Abstract

A series of functionalized nanographitic carbons is prepared, characterized and tested in fructose dehydration reaction to 5-hydroxymethylfurfural. The functionalization treatment was selected to introduce various Brönsted acid sites and to modify the textural and catalytic properties of the initial carbon material. Within the series, the sulfonated carbons present the most interesting catalytic behavior resulting in important selectivity to the desired product once the reaction variables were properly adjusted.

Ministerio de Economía y Competitividad de España (MINECO) y fondos FEDER de la Unión Europea-ENE2017- 82451-C3-1-R y ENE2017-82451-C3-3-R

Country

Spain

Related Organizations

Spanish National Research Council
Spain
University of Seville
Spain
University Ferhat Abbas of Setif
Algeria
University of Zaragoza
Spain

Keywords

5-hydroxymethylfurfural, P-toluenesulfonic acid, Fructose dehydration, Nanographitic carbon, Functionalization

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