The biotransformation of the diterpene 2β-hydroxy-ent-13-epi-manoyl oxide by Gibberella fujikuroi

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2003 Spain English Publisher:Elsevier BVJournal:Phytochemistry, volume 62, pages 67-70 (issn: 0031-9422,

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Authors: Fraga, Braulio M.; González, Pedro; Hernández, Melchor G.; Suárez, Sergio;

doi: 10.1016/s0031-9422(02)00436-3

pmid: 12475620

handle: 10261/21566

The biotransformation of the diterpene 2β-hydroxy-ent-13-epi-manoyl oxide by Gibberella fujikuroi

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Abstract

Incubation of the diterpene 2beta-hydroxy-ent-13-epi-manoyl oxide with Gibberella fujikuroi afforded in good yield 2beta,6beta-dihydroxy-ent-13-epi-manoyl oxide, 2beta,12beta-dihydroxy-ent-13-epi-manoyl oxide and 2beta,20-dihydroxy-ent-13-epi-manoyl oxide, confirming that although ent-13-epi-manoyl oxide is a final metabolite of a biosynthetic branch in this fungus, more polar derivatives of this compound can be transformed by this micro-organism.

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Spain

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Keywords

Magnetic Resonance Spectroscopy, Molecular Structure, Gibberella, Terpenes, 2B-Hydroxy-ent-13-epi-manoyl oxide, Gibberella fujokuroi, Fermentation, Diterpenes, Biotransformation

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